Complex Organics Molecules are Bubbling up From Inside Enceladus

The Cassini orbiter revealed many fascinating things about the Saturn system before its mission ended in September of 2017. In addition to revealing much about Saturn’s rings and the surface and atmosphere of Titan (Saturn’s largest moon), it was also responsible for the discovery of water plumes coming from Enceladus‘ southern polar region. The discovery of these plumes triggered a widespread debate about the possible existence of life in the moon’s interior.

This was based in part on evidence that the plumes extended all the way to the moon’s core/mantle boundary and contained elements essential to life. Thanks to a new study led by researchers from of the University of Heidelberg, Germany, it has now been confirmed that the plumes contain complex organic molecules. This is the first time that complex organics have been detected on a body other than Earth, and bolsters the case for the moon supporting life.

The study, titled “Macromolecular organic compounds from the depths of Enceladus“, recently appeared in the journal Nature. The study was led by Frank Postberg and Nozair Khawaja of the Institute for Earth Sciences at the University of Heidelberg, and included members from the Leibniz Institute of Surface Modification (IOM), the Southwest Research Institute (SwRI), NASA’s Jet Propulsion Laboratory, and multiple universities.

The existence of a liquid water ocean in Enceladus’ interior has been the subject of scientific debate since 2005, when Cassini first observed plumes containing water vapor spewing from the moon’s south polar surface through cracks in the surface (nicknamed “Tiger Stripes”). According to measurements made by the Cassini-Huygens probe, these emissions are composed mostly of water vapor and contain molecular nitrogen, carbon dioxide, methane and other hydrocarbons.

The combined analysis of imaging, mass spectrometry, and magnetospheric data also indicated that the observed southern polar plumes emanate from pressurized subsurface chambers. This was confirmed by the Cassini mission in 2014 when the probe conducted gravity measurements that indicated the existence of a south polar subsurface ocean of liquid water with a thickness of around 10 km.

Shortly before the probe plunged into Saturn’s atmosphere, the probe also obtained data that indicated that the interior ocean has existed for some time. Thanks to previous readings that indicated the presence of hydrothermal activity in the interior and simulations that modeled the interior, scientists concluded that if the core were porous enough, this activity could have provided enough heat to maintain an interior ocean for billions of years.

However, all the previous studies of Cassini data were only able to identify simple organic compounds in the plume material, with molecular masses mostly below 50 atomic mass units. For the sake of their study, the team observed evidence of complex macromolecular organic material in the plumes’ icy grains that had masses above 200 atomic mass units.

This constitutes the first-ever detection of complex organics on an extraterrestrial body. As Dr. Khawaja explained in a recent ESA press release:

“We found large molecular fragments that show structures typical for very complex organic molecules. These huge molecules contain a complex network often built from hundreds of atoms of carbon, hydrogen, oxygen and likely nitrogen that form ring-shaped and chain-like substructures.”

The molecules that were detected were the result of the ejected ice grains hitting the dust-analyzing instrument aboard Cassini at speeds of about 30,000 km/hour. However, the team believes that these were mere fragments of larger molecules contained beneath Enceladus’ icy surface. As they state in their study, the data suggests that there is a thin organic-rich film on top of the ocean.

These large molecules would be the result of by complex chemical processes, which could be those related to life. Alternately, they may be derived from primordial material similar to what has been found in some meteorites or (as the team suspects) that is generated by hydrothermal activity. As Dr. Postberg explained:

“In my opinion the fragments we found are of hydrothermal origin, having been processed inside the hydrothermally active core of Enceladus: in the high pressures and warm temperatures we expect there, it is possible that complex organic molecules can arise.”

Further Reading: ESA, Nature