China's Lunar Samples Contain Graphene Flakes

Artist’s impression of the graphenes (C24) and fullerenes found in a Planetary Nebula. The detection of graphenes and fullerenes around old stars as common as our Sun suggests that these molecules and other allotropic forms of carbon may be widespread in space. Credits: IAC; original image of the Helix Nebula (NASA, NOAO, ESA, the Hubble Helix Nebula Team, M. Meixner, STScI, & T.A. Rector, NRAO.)

In 2004, scientists at the University of Manchester first isolated and investigated graphene, the supermaterial composed of single-layer carbon atoms arranged in a hexagonal honeycomb lattice. Since then, it has become a wonder, with properties that make it extremely useful in numerous applications. Among scientists, it is generally believed that about 1.9% of carbon in the interstellar medium (ISM) exists in the form of graphene, with its shape and structure determined by the process of its formation.

As it happens, there could be lots of this supermaterial on the surface of the Moon. In a recent study, researchers from the Chinese Academy of Science (CAS) revealed naturally formed graphene arranged in a special thin-layered structure on the Moon. These findings could have drastic implications for our understanding of how the Moon formed and lead to new methods for the manufacture of graphene, with applications ranging from electronics, power storage, construction, and supermaterials. They could also prove useful for future missions that will create permanent infrastructure on the lunar surface.

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Glass Fibers in Lunar Regolith Could Help Build Structures on the Moon

Electron microscope images of various glass particles identified from China's Chang'e-5 lunar samples. Credit: Laiquan Shen, R.Z. et al. (2023)

Through the Artemis Program, NASA plans to send the first astronauts to the Moon in over fifty years. Before the decade is over, this program aims to establish the infrastructure that will allow for a “sustained program of lunar exploration and development.” The European Space Agency (ESA) also has big plans, which include the creation of a Moon Village that will serve as a spiritual successor to the International Space Station (ISS). China and Roscosmos also came together in June 2021 to announce that they would build the International Lunar Research Station (ILRS) around the lunar south pole.

In all cases, space agencies plan to harvest local resources to meet their construction and long-term needs – a process known as In-Situ Resource Utilization (ISRU). Based on samples returned by the fifth mission of the Chinese Lunar Exploration Program (Chang’e-5), a team of researchers from the Chinese Academy of Sciences (CAS) identified indigenous glass fibers for the first time. According to a paper they authored, these fibers were formed by past impacts in the region and could be an ideal building material for future lunar bases.

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Researchers Make Rocket Fuel Using Actual Regolith From the Moon

In-situ resource utilization is a hot topic these days in space exploration circles, and scientists and engineers have had a great advantage of getting access to new materials from bodies on the solar system that either have never been seen before, such as asteroids or haven’t been visited in decades, such as the moon. Recently, China’s Chang’e 5 brought back the first sample of lunar regolith to Earth in almost 50 years. Using part of that sample, researchers from several Chinese universities have developed an automated system to create rocket fuel and oxygen out of CO2, using the lunar regolith as a catalyst.

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The Moon had Volcanoes More Recently Than Previously Believed

New measurements of lunar rocks have demonstrated that the ancient moon generated a dynamo magnetic field in its liquid metallic core (innermost red shell). The results raise the possibility of two different mechanisms — one that may have driven an earlier, much stronger dynamo, and a second that kept the moon’s core simmering at a much slower boil toward the end of its lifetime. Credit: Hernán Cañellas/Benjamin Weiss

Fifty years ago, NASA and the Soviet space program conducted the first sample-return missions from the Moon. This included lunar rocks brought back to Earth by the Apollo astronauts and those obtained by robotic missions that were part of the Soviet Luna Program. The analysis of these rocks revealed a great deal about the Moon’s composition, formation, and geological history. In particular, scientists concluded that the rocks were formed from volcanic eruptions more than three billion years ago.

In recent years, there has been a resurgence in lunar exploration as NASA and other space agencies have sent robotic missions to the Moon (in preparation for crewed missions). For instance, China has sent multiple orbiters, landers, and rovers to the Moon as part of the Chang’e program, including sample-return missions. A new study led by planetary scientists from the Chinese Academy of Sciences (CAS) analyzed samples obtained by the Chang’e-5 rover dated to two billion years ago. Their research could provide valuable insight into how young volcanism shaped the lunar surface.

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China’s Lunar Lander Finds Water Under its Feet

The area marked by the red line are the scoop sampling points, the blue box identifies the imaging area of the panoramic camera and the base image is from landing camera. Credit: Chinese Academy of Sciences.

Earlier this year, scientists from China’s Chang’E-5 lunar lander revealed they had found evidence of water in the form of hydroxyl from in-situ measurements taken while lander was on the Moon. Now, they have confirmed the finding with laboratory analysis of the lunar samples from Chang’E-5 that were returned to Earth.  The amount of water detected varied across the randomly chosen samples taken from around the base of the lander, from 0 to 180 parts per million (ppm), mean value of 28.5?ppm, which is on the weak end of lunar hydration.

“For the first time in the world, the results of laboratory analysis of lunar return samples and spectral data from in-situ lunar surface surveys were used jointly to examine the presence, form and amount of ‘water’ in lunar samples,” said co-author Li Chunlai from the National Astronomical Observatories of the Chinese Academy of Sciences (NAOC), in a press release. “The results accurately answer the question of the distribution characteristics and source of water in the Chang’E-5 landing zone and provide a ground truth for the interpretation and estimation of water signals in remote sensing survey data.”

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China’s Lander Has Detected Water on the Moon

Illustration: Chang'e-5 probe
An artist's concept shows the Chang'e-5 lander and ascent vehicle on the Moon. (CNSA / CLEP via NASA)

China’s Chang’e-5 lunar lander has found evidence of hydroxyl (OH) on the Moon. Hydroxyl is a close chemical cousin of water, H2O. While several other orbital missions have detected OH on the Moon previously, Chang’e-5 marks the first time it has been detected by a spacecraft sitting on the lunar surface.

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Chang’e-5 Returned an Exotic Collection of Moon Rocks

Image of the Chang’e-5 sample “CE5C0400” from the Moon’s surface. This fraction of lunar materials returned to Earth by Chang’e-5 weighs nearly 35 grams and was collected by a robotic arm. Credit: CNSA (China National Space Administration) / CLEP (China Lunar Exploration Program) / GRAS (Ground Research Application System).

Scientists have begun studying the samples returned from the Moon by China’s Chang’e-5 mission in December 2020, and a group of researchers presented their first findings at the Europlanet Science Congress (EPSC) last week.

“The Chang’e-5 samples are very diverse, and includes both local and exotic materials, including some glutenates [sharp, jagged lunar particles], silicas, salts, volcanic glasses, and impact glasses, along with different minerals and different rock types,” said Yuqi Qian, a PhD student at the China University of Geosciences, during his presentation at the EPSC virtual meeting.

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Chang’e-5 Brought Home 1.7 Kilograms of Lunar Samples

Chinese scientists open the sample container from the Chang-e-5 lunar sample return mission. Credit: Xinhua

China’s Chang’e-5 lunar lander retrieved about 1.7 kilograms (3.81 pounds) of samples from the Moon, according to the China National Space Administration (CNSA).  The Chang’e-5 sample return capsule landed in China’s Inner Mongolia region on December 16, 2020, successfully capping a 23-day odyssey that brought back the first lunar rocks since 1976.

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Here’s Chang’e-5, Seen From Lunar Orbit

Credit: NASA/GSFC/Arizona State University

On Tuesday, December 1st, at 10:11 EST (07:00 PST) the Chang’e-5 sample return spacecraft landed safely on the Moon. This mission is the latest in China’s lunar exploration program, which is paving the way for the creation of a lunar outpost and a crewed mission by the 2030s. The day after it landed, the Lunar Reconnaissance Orbiter (LRO) passed over the site and acquired an image of the lander.

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Chinese Spacecraft Dock in Lunar Orbit for Transfer of Moon Samples – Next Stop, Earth!

Chang'e-5's orbiter approaches the lunar ascent vehicle for docking. (CLEP / CNSA Photo)

Two robotic Chinese spacecraft have docked in lunar orbit for the first time ever, in preparation for sending samples from the Moon to Earth.

The lunar ascent module for China’s Chang’e-5 mission was captured by the metal claws of the mission’s orbiter at 5:42 a.m. Beijing time December 6th (2142 UTC December 5th), the China National Space Administration reported.

Over the half-hour that followed, a canister containing lunar material was safely transferred to the orbiter’s attached Earth-return capsule. In the days ahead, the ascent module will be jettisoned, and the orbiter will fire its thrusters to carry the return capsule back toward Earth.

If all proceeds according to plan, the orbiter will drop off the return capsule for its descent to Inner Mongolia sometime around December 16th, with the exact timing dependent on the mission team’s analysis of the required trajectory. That would mark the first return of fresh material from the Moon since the Soviet Luna 24 spacecraft accomplished the feat back in 1976.

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