China's Lunar Samples Contain Graphene Flakes

Artist’s impression of the graphenes (C24) and fullerenes found in a Planetary Nebula. The detection of graphenes and fullerenes around old stars as common as our Sun suggests that these molecules and other allotropic forms of carbon may be widespread in space. Credits: IAC; original image of the Helix Nebula (NASA, NOAO, ESA, the Hubble Helix Nebula Team, M. Meixner, STScI, & T.A. Rector, NRAO.)

In 2004, scientists at the University of Manchester first isolated and investigated graphene, the supermaterial composed of single-layer carbon atoms arranged in a hexagonal honeycomb lattice. Since then, it has become a wonder, with properties that make it extremely useful in numerous applications. Among scientists, it is generally believed that about 1.9% of carbon in the interstellar medium (ISM) exists in the form of graphene, with its shape and structure determined by the process of its formation.

As it happens, there could be lots of this supermaterial on the surface of the Moon. In a recent study, researchers from the Chinese Academy of Science (CAS) revealed naturally formed graphene arranged in a special thin-layered structure on the Moon. These findings could have drastic implications for our understanding of how the Moon formed and lead to new methods for the manufacture of graphene, with applications ranging from electronics, power storage, construction, and supermaterials. They could also prove useful for future missions that will create permanent infrastructure on the lunar surface.

Continue reading “China's Lunar Samples Contain Graphene Flakes”

Was There a Time When the Moon was Habitable?

Artist's concept of a terraformed moon. According to a new study, the Moon may have had periods of habitability in its past where it had an atmosphere and liquid water on its surface. Credit: Ittiz

To put it simply, the Earth’s Moon is a dry, airless place where nothing lives. Aside from concentrations of ice that exist in permanently-shaded craters in the polar regions, the only water on the moon is believed to exist beneath the surface. What little atmosphere there is consists of elements released from the interior (some of which are radioactive) and helium-4 and neon, which are contributed by solar wind.

However, astronomers have theorized that there may have been a time when the Moon might have been inhabitable. According to a new study by an astrophysicist and an Earth and planetary scientist, the Moon may have had two early “windows” for habitability in the past. These took place roughly 4 billion years ago (after the Moon formed) and during the peak in lunar volcanic activity (ca. 3.5 billion years ago).

Continue reading “Was There a Time When the Moon was Habitable?”

Good News, Martian Colonists Can Eat All the Radishes They Want

Screenshot from the The Martian, showing character Mark Watney tend to his Martian potato crop. Credit: Twentieth Century Fox Film Corporation

When your stated purpose is to send settlers to Mars by 2026, you’re sure to encounter a lot of skepticism. And that is exactly what Dutch entrepreneur Bas Lansdorp has been dealing with ever since he first went public with MarsOne in 2012. In fact, in the past four years, everything from the project’s schedule, technical and financial feasibility, and ethics have been criticized by scientists, engineers and people in the aerospace industry.

However, Lansdorp and his organization have persevered, stating that they intend to overcome all the challenges in sending people on a one-way trip to the Red Planet. And in their most recent statement, MarsOne has announced that they have addressed the all-important issue of what their settlers will eat. In an experiment that feels like it was ripped from the The Martian, MarsOne has completed testing different types of crops in simulated Martian soil, to see which ones could grow on Mars.

Located in the Dutch town of Nergena, MarsOne maintains a glasshouse complex where they have been conducting experiments. These experiments took place in 2013 and 2015, and involved Martian and Lunar soil simulants provided by NASA, along with Earth soil as a control group.

Artist's impression of a Martian greenhouse. Credit: NASA/Human Systems Engineering and Development Division
A conceptual rendering of a Martian greenhouse. Credit: NASA/Human Systems Engineering and Development Division

Using these, a team of ecologists and crop scientists from the Wageningen University & Research Center have been testing different kinds of seeds to see which ones will grow in a Lunar and Martian environment. These have included rye, radishes, garden cress and pea seed. And earlier this year, they added a crop of tomatoes and potatoes to the mix.

As Dr. Wieger Wamelink, the ecologist who led the experiments, told Universe Today via email:

“We started our first experiment in 2013 (published in Plos One in 2014) to investigate if it was possible to grow plants in Mars and moon soil simulants. We assume that plants will be grown indoors, because of the very harsh circumstances on both Mars and moon, very cold, no or almost no atmosphere and way to much cosmic radiation. That first experiment only had a few crops and mostly wild plants and clovers (for nitrogen binding from the atmosphere to manure the soil).”

After confirming that the seeds would germinate in the simulated soil after the first year, they then tested to see if the seeds from that harvest would germinate in the same soil to create another harvest. What they found was quite encouraging. In all four cases, the seeds managed to germinate nicely in both Martian and Lunar soil.

Researchers at Wageningen University in the Netherlands have harvested tomatoes and other vegetables grown in simulated Martian soil. Image: regan76 CC BY 2.0
Researchers at Wageningen University in the Netherlands have harvested tomatoes and other vegetables grown in simulated Martian soil. Credit: regan76 CC BY 2.0

“Our expectation were very low,” said Wamelink, “so we were very surprised that on the Mars soil simulant plants grew rather well and even better than on our nutrient poor control earth soil. There were also problems, the biggest that it was very difficult to keep the soil moist and that though on Mars soil simulant there was growth it was not very good, i.e. the amount of biomass formed was low.”

And while they didn’t grow as well as the control group, which was grown in Earth soil, they did managed to produce time and again. This was intrinsic to the entire process, in order to make sure that any crops grown on Mars would have a full life-cycle. Being able to grow crops, replant seeds, and grow more would eliminate the need to bring new seeds for every crop cycle, thus ensuring that Martian colonists could be self-sufficient when it came to food.

In 2015, they conducted their second experiment. This time around, after planting the seeds in the simulated soil, they added organic matter to simulate the addition of organic waste from a previous crop cycle. And on every Friday, when the experiments were running, they added nutrient solution to mimic the nutrients derived from fecal matter and urine (definite echoes of The Martian there!).

Once again, the results were encouraging. Once again, the crops grew, and the addition or organic matter improved the soil’s water-holding capacity. Wamelink and his team were able to harvest from many of the ten crops they had used in the experiment, procuring another batch of radishes, tomatoes and peas. The only crop that did poorly was the batch of spinach they had added.

This year, the team’s experiments were focused on the issue of food safety. As any ecologist knows, plants naturally absorb minerals from their surrounding environment. And tests have shown that soils obtained from the Moon and Mars show concentrations of heavy metals and toxins  – such as arsenic, cadmium, copper, lead, and iron (which is what gives Mars its reddish appearance). As Wamelink described the process:

Again we have ten crops, but slightly different crops from last year; we included green beans and potatoes (best food still and Mark Watney also seems to love potatoes). Also repeated was the addition of organic matter, to mimic the addition of the plant parts that are not eaten from a previous growth cycle. Also new is the addition of liquid manure, to mimic the addition of human faeces… We know that both Mars and moon soil simulants contain heavy metals, like led, copper, mercury and chrome. The plants do not care about this, however when they end up in the eaten parts then they could poison the humans that eat them. There we have to test if it is safe to eat them.”

And again, the results were encouraging. In all cases, the crops showed that the concentrations of metals they contained were within human tolerances and therefore safe to eat. In some cases, the metal concentrations were even lower than that found those grown using potting soil.

“We now tested four species we harvested last year as a preliminary investigation and it shows that luckily there are no harmful quantities present in the fruits, so it is safe to eat them,” said Wamelink. “We will continue these analyses, because for the FDA they have to be analysed in fresh fruits and vegetables, where we did the analyses on dried material. Moreover we will also look at the content of large molecules, like vitamins, flavonoids (for the taste) and alkaloids (for toxic components).”

However, the Wageningen UR team hopes to test all ten of the crops they have grown in order to make sure that everything grown in Martian soil will be safe to eat. Towards this end, Wageningen UR has set up a crowdfunding campaign to finance their ongoing experiments. With public backing, they hope to show that future generations will be able to be self-sufficient on Mars, and not have to worry about things like arsenic and lead poisoning.

As an incentive, donors will receive a variety of potential gifts, which include samples of the soil simulant used for the experiment. But the top prize, a a dinner based on the harvest, is being offered to people contributing €500 ($555.90 USD) or more. In what is being called the first “Martian meal” this dinner will take place once the experiment is complete and will of course include Martian potatoes!

Looking ahead, Wamelink and his associates also hope to experiment crops that do not rely on a seed-to-harvest cycle, and are not harvested annually.These include fruit trees so that they might be able to grow apples, cherries, and strawberries in Martian soil. In addition, Wamelink has expressed interest in cultivating lupin seeds as a means of replacing meat in the Martian diet.

And when it comes right down to it, neither MarsOne or the Wageningen UR team are alone in wanting to see what can be grown on Mars or other planets. For years, NASA has also been engaged in their own tests to see which crops can be cultivated on Mars. And with the help of the Lima-based International Potato Center, their latest experiment involves cultivating potatoes in samples of Peruvian soil.

Artist's concept of a Martian astronaut standing outside the Mars One habitat. Credit: Bryan Versteeg/Mars One
Artist’s concept of a Martian astronaut standing outside the Mars One habitat. Credit: Bryan Versteeg/Mars One

For hundreds of years, the Andean people have been cultivating potatoes in the region. And given the arid conditions, NASA believes it will serve as a good facsimile for Mars. But perhaps the greatest draw is the fact cultivating potatoes in a simulated Martian environment immediately calls to mind Matt Damon in The Martian. In short, it’s a spectacular PR move that NASA, looking to drum up support for its “Journey to Mars“, cannot resist!

Naturally, experiments such as these are not just for the sake of meeting the challenges posed by MarsOne’s plan for one-way crewed missions to Mars. Alongside the efforts of NASA and others, they are part of a much larger effort to address the challenges posed by the renewed era of space exploration we find ourselves embarking on.

With multiple space agencies and private corporations (like SpaceX) hoping to put buts back on the Moon and Mars, and to establish permanent bases on these planets and even in the outer Solar System, knowing what it will take for future generations of colonists and explorers to sustain themselves is just good planning.

Further Reading: Mars Exchange

Scientists Identify the Source of the Moon’s Water

New research finds that asteroids delivered as much 80 percent of the Moon's water. Credit: LPI/David A. Kring

Over the course of the past few decades, our ongoing exploration the Solar System has revealed some surprising discoveries. For example, while we have yet to find life beyond our planet, we have discovered that the elements necessary for life (i.e organic molecules, volatile elements, and water) are a lot more plentiful than previously thought. In the 1960’s, it was theorized that water ice could exist on the Moon; and by the next decade, sample return missions and probes were confirming this.

Since that time, a great deal more water has been discovered, which has led to a debate within the scientific community as to where it all came from. Was it the result of in-situ production, or was it delivered to the surface by water-bearing comets, asteroids and meteorites? According to a recent study produced by a team of scientists from the UK, US and France, the majority of the Moon’s water appears to have come from meteorites that delivered water to Earth and the Moon billions of years ago.

For the sake of their study, which appeared recently in Nature Communications, the international research team examined the samples of lunar rock and soil that were returned by the Apollo missions. When these samples were originally examined upon their return to Earth, it was assumed that the trace of amounts of water they contained were the result of contamination from Earth’s atmosphere since the containers in which the Moon rocks were brought home weren’t airtight. The Moon, it was widely believed, was bone dry.

The blue areas show locations on the Moon's south pole where water ice is likely to exist (NASA/GSFC)
The blue areas show locations on the Moon’s south pole where water ice is likely to exist. Credit: NASA/GSFC

However, a 2008 study revealed that the samples of volcanic glass beads contained water molecules (46 parts per million), as well as various volatile elements (chlorine, fluoride and sulfur) that could not have been the result of contamination. This was followed up by the deployment of the Lunar Reconnaissance Orbiter (LRO) and the Lunar Crater Observation and Sensing Satellite (LCROSS) in 2009, which discovered abundant supplies of water around the southern polar region,

However, that which was discovered on the surface paled in comparison the water that was discovered beneath it. Evidence of water in the interior was first revealed by the ISRO’s Chandrayaan-1 lunar orbiter – which carried the NASA’s Moon Mineralogy Mapper (M3) and delivered it to the surface. Analysis of this and other data has showed that water in the Moon’s interior is up to a million times more abundant than what’s on the surface.

The presence of so much water beneath the surface has begged the question, where did it all come from? Whereas water that exists on the Moon’s surface in lunar regolith appears to be the result of interaction with solar wind, this cannot account for the abundant sources deep underground. A previous study suggested that it came from Earth, as the leading theory for the Moon’s formation is that a large Mars-sized body impacted our nascent planet about 4.5 billion years ago, and the resulting debris formed the Moon. The similarity between water isotopes on both bodies seems to support that theory.

Near-infrared image of the Moon's surface by NASA's Moon Mineralogy Mapper on the Indian Space Research Organization's Chandrayaan-1 mission Image credit: ISRO/NASA/JPL-Caltech/Brown Univ./USGS
Near-infrared image of the Moon’s surface by NASA’s Moon Mineralogy Mapper on the Indian Space Research Organization’s Chandrayaan-1 mission. Credit: ISRO/NASA/JPL-Caltech/Brown Univ./USGS

However, according to Dr. David A. Kring, a member of the research team that was led by Jessica Barnes from Open University, this explanation can only account for about a quarter of the water inside the moon. This, apparently, is due to the fact that most of the water would not have survived the processes involved in the formation of the Moon, and keep the same ratio of hydrogen isotopes.

Instead, Kring and his colleagues examined the possibility that water-bearing meteorites delivered water to both (hence the similar isotopes) after the Moon had formed. As Dr. Kring told Universe Today via email:

“The current study utilized analyses of lunar samples that had been collected by the Apollo astronauts, because those samples provide the best measure of the water inside the Moon. We compared those analyses with analyses of meteoritic samples from asteroids and spacecraft analyses of comets.”

By comparing the ratios of hydrogen to deuterium (aka. “heavy hydrogen”) from the Apollo samples and known comets, they determined that a combination of primitive meteorites (carbonaceous chondrite-type) were responsible for the majority of water to be found in the Moon’s interior today. In addition, they concluded that these types of comets played an important role when it comes to the origins of water in the inner Solar System.

These images produced by the Lyman Alpha Mapping Project (LAMP) aboard NASA's Lunar Reconnaissance Orbiter reveal features at the Moon's northern and southern poles in the regions that lie in perpetual darkness. They show regions that are consistent with having large surface porosities — indicating "fluffy" soils — while the reddening is consistent with the presence of water frost on the surface. Credit: Southwest Research Institute
Images produced by the Lyman Alpha Mapping Project (LAMP) aboard NASA’s Lunar Reconnaissance Orbiter reveal features at the Moon’s northern and southern poles, as well as the presence of water frost. Credit: NASA/SwRI

For some time, scientists have argued that the abundance of water on Earth may be due in part to impacts from comets, trans-Neptunian objects or water-rich meteoroids. Here too, this was based on the fact that the ratio of the hydrogen isotopes (deuterium and protium) in asteroids like 67P/Churyumov-Gerasimenko revealed a similar percentage of impurities to carbon-rich chondrites that were found in the Earth’s coeans.

But how much of Earth’s water was delivered, how much was produced indigenously, and whether or not the Moon was formed with its water already there, have remained the subject of much scholarly debate. Thank to this latest study, we may now have a better idea of how and when meteorites delivered water to both bodies, thus giving us a better understanding of the origins of water in the inner Solar System.

Some meteoritic samples of asteroids contain up to 20% water,” said Kring. “That reservoir of material – that is asteroids – are closer to the Earth-Moon system and, logically, have always been a good candidate source for the water in the Earth-Moon system. The current study shows that to be true. That water was apparently delivered 4.5 to 4.3 billion years ago.

The existence of water on the Moon has always been a source of excitement, particularly to those who hope to see a lunar base established there someday. By knowing the source of that water, we can also come to know more about the history of the Solar System and how it came to be. It will also come in handy when it comes time to search for other sources of water, which will always be a factor when trying to establishing outposts and even colonies throughout the Solar System.

Further Reading: Nature Communications

What is Lunar Regolith?

A boot print on the lunar regolith. Credit: NASA.

When you’re walking around on soft ground, do you notice how your feet leave impressions? Perhaps you’ve tracked some of the looser earth in your yard into the house on occasion? If you were to pick up some of these traces – what we refer to as dirt or soil – and examine them beneath a microscope, what would you see?

Essentially, you would be seeing the components of what is known as regolith, which is a collection of particles of dust, soil, broken rock, and other materials found here on Earth. But interestingly enough, this same basic material can be found in other terrestrial environments as well – including the Moon, Mars, other planets, and even asteroids.

Definition:

The term regolith refers to any layer of material covering solid rock, which can come in the form of dust, soil or broken rock. The word is derived from the combination of two Greek words – rhegos (which means “blanket”) and lithos (which means “rock).

Earth:

On Earth, regolith takes the form of dirt, soil, sand, and other components that are formed as a result of natural weathering and biological processes. Due to a combination of erosion, alluvial deposits (i.e. moving water deposing sand), volcanic eruptions, or tectonic activity, the material is slowly ground down and laid out over solid bedrock.

central Yilgarn Craton, Western Australia.
Picture of Mt Magnet in the Central Yilgarn Craton in Western Australia, which dates to the Precambrian Era. Credit: geomorphologie.revues.org

It can be made up of clays, silicates, various minerals, groundwater, and organic molecules. Regolith on Earth can vary from being essentially absent to being hundreds of meters thick. Its can also be very young (in the form of ash, alluvium, or lava rock that was just deposited) to hundreds of millions of years old (regolith dating to the Precambrian age occurs in parts of Australia).

On Earth, the presence of regolith is one of the important factors for most life, since few plants can grow on or within solid rock and animals would be unable to burrow or build shelter without loose material. Regolith is also important for human beings since it has been used since the dawn of civilization (in the form of mud bricks, concrete and ceramics) to build houses, roads, and other civil works.

The difference in terminology between “soil” (aka. dirt, mud, etc.) and “sand” is the presence of organic materials. In the former, it exists in abundance, and is what separates regolith on Earth from most other terrestrial environments in our Solar System.

The Moon:

The surface of the Moon is covered with a fine powdery material that scientists refer to it as “lunar regolith”. Nearly the entire lunar surface is covered with regolith, and bedrock is only visible on the walls of very steep craters.

Earth viewed from the Moon by the Apollo 11 spacecraft. Credit: NASA
Earth viewed from the Moon by the Apollo 11 spacecraft, across a sea of lunar soil. Credit: NASA

The Moon regolith was formed over billions of years by constant meteorite impacts on the surface of the Moon. Scientists estimate that the lunar regolith extends down 4-5 meters in some places, and even as deep as 15 meters in the older highland areas.

When the plans were put together for the Apollo missions, some scientists were concerned that the lunar regolith would be too light and powdery to support the weight of the lunar lander. Instead of landing on the surface, they were worried that the lander would just sink down into it like a snowbank.

However, landings performed by robotic Surveyor spacecraft showed that the lunar soil was firm enough to support a spacecraft, and astronauts later explained that the surface of the Moon felt very firm beneath their feet. During the Apollo landings, the astronauts often found it necessary to use a hammer to drive a core sampling tool into it.

Once astronauts reached the surface, they reported that the fine moon dust stuck to their spacesuits and then dusted the inside of the lunar lander. The astronauts also claimed that it got into their eyes, making them red; and worse, even got into their lungs, giving them coughs. Lunar dust is very abrasive, and has been noted for its ability to wear down spacesuits and electronics.

Alan Bean Takes Lunar Soil Sample
Alan Bean takes a sample of lunar regolith during the Apollo 12 mission. Credit: NASA

The reason for this is because lunar regolith is sharp and jagged. This is due to the fact that the Moon has no atmosphere or flowing water on it, and hence no natural weathering process. When the micro-meteoroids slammed into the surface and created all the particles, there was no process for wearing down its sharp edges.

The term lunar soil is often used interchangeably with “lunar regolith”, but some have argued that the term “soil” is not correct because it is defined as having organic content. However, standard usage among lunar scientists tends to ignore that distinction. “Lunar dust” is also used, but mainly to refer to even finer materials than lunar soil.

As NASA is working on plans to send humans back to the Moon in the coming years, researchers are working to learn the best ways to work with the lunar regolith. Future colonists could mine minerals, water, and even oxygen out of the lunar soil, and use it to manufacture bases with as well.

Mars:

Landers and rovers that have been sent to Mars by NASA, the Russians and the ESA have returned many interesting photographs, showing a landscape that is covered with vast expanses of sand and dust, as well as rocks and boulders.

A successful scoop of Martian regolith (NASA/JPL-Caltech/University of Arizona/Max Planck Institute)
A successful scoop of Martian regolith performed by NASA’s Phoenix lander. Credit: NASA/JPL-Caltech/University of Arizona/Max Planck Institute

Compared to lunar regolith, Mars dust is very fine and enough remains suspended in the atmosphere to give the sky a reddish hue. The dust is occasionally picked up in vast planet-wide dust storms, which are quite slow due to the very low density of the atmosphere.

The reason why Martian regolith is so much finer than that found on the Moon is attributed to the flowing water and river valleys that once covered its surface. Mars researchers are currently studying whether or not martian regolith is still being shaped in the present epoch as well.

It is believed that large quantities of water and carbon dioxide ices remain frozen within the regolith, which would be of use if and when manned missions (and even colonization efforts) take place in the coming decades.

Mars moon of Deimos is also covered by a layer of regolith that is estimated to be 50 meters (160 feet) thick. Images provided by the Viking 2 orbiter confirmed its presence from a height of 30 km (19 miles) above the moon’s surface.

Asteroids and Outer Solar System:

The only other planet in our Solar System that is known to have regolith is Titan, Saturn’s largest moon. The surface is known for its extensive fields of dunes, though the precise origin of them are not known. Some scientists have suggested that they may be small fragments of water ice eroded by Titan’s liquid methane, or possibly particulate organic matter that formed in Titan’s atmosphere and rained down on the surface.

Another possibility is that a series of powerful wind reversals, which occur twice during a single Saturn year (30 Earth years), are responsible for forming these dunes, which measure several hundred meters high and stretch across hundreds of kilometers.  Currently, Earth scientists are still not certain what Titan’s regolith is composed of.

Data returned by the Huygens Probe’s penetrometer indicated that the surface may be clay-like, but long-term analysis of the data has suggested that it may be composed of sand-like ice grains.  The images taken by the probe upon landing on the moon’s surface show a flat plain covered in rounded pebbles, which may be made of water ice, and suggest the action of moving fluids on them.

Asteroids have been observed to have regolith on their surfaces as well. These are the result of meteoriod impacts that have taken place over the course of millions of years, pulverizing their surfaces and creating dust and tiny particles that are carried within the craters.

False color picture of Eros' 5.3-kilometer (3.3-mile) surface crater, showing regolith inside. Credit: NASA/JPL/JHUAPL
False color picture taken by NASA’s NEAR Shoemaker camera of Eros’ 5.3-kilometer (3.3-mile) surface crater, showing the presence of regolith inside. Credit: NASA/JPL/JHUAPL

NASA’s NEAR Shoemaker spacecraft produced evidence of regolith on the surface of the asteroid 433 Eros, which remains the best images of asteroid regolith to date. Additional evidence has been provided by JAXA’s Hayabusa mission, which returned clear images of regolith on an asteroid that was thought to be too small to hold onto it.

Images provided by the Optical, Spectroscopic, and Infrared Remote Imaging System (OSIRIS) cameras on board the Rosetta Spacecraft confirmed that the asteroid 21 Lutetia has a layer of regolith near its north pole, which was seen to flow in major landslides associated with variations in the asteriod’s albedo.

To break it down succinctly, wherever there is rock, there is likely to be regolith. Whether it is the product of wind or flowing water, or the presence of meteors impacting the surface, good old fashioned “dirt” can be found just about anywhere in our Solar System; and most likely, in the universe beyond…

We’ve done several articles about the Moon’s regolith here on Universe Today. Here’s a way astronauts might be able to extract water from lunar regolith with simple kitchen appliances, and an article about NASA’s search for a lunar digger.

Want to buy some lunar regolith simulant? Here’s a site that lets you buy it. Do you want to be a Moon miner? There’s lots of good metal in that lunar regolith.

You can listen to a very interesting podcast about the formation of the Moon from Astronomy Cast, Episode 17: Where Did the Moon Come From?

Reference:
NASA