Using two diamonds, scientists squeezed hydrogen to pressures above those in Earth's core. Credit: Sang-Heon Shim, Arizona State University
Scientists have long speculated that at the heart of a gas giant, the laws of material physics undergo some radical changes. In these kinds of extreme pressure environments, hydrogen gas is compressed to the point that it actually becomes a metal. For years, scientists have been looking for a way to create metallic hydrogen synthetically because of the endless applications it would offer.
At present, the only known way to do this is to compress hydrogen atoms using a diamond anvil until they change their state. And after decades of attempts (and 80 years since it was first theorized), a team of French scientists may have finally created metallic hydrogen in a laboratory setting. While there is plenty of skepticism, there are many in scientific community who believe this latest claim could be true.
Now, don’t get me wrong, Science Fiction is awesome. Like almost everyone working in the field of space and astronomy, I was deeply influenced by science fiction. For me, it was Star Trek and Star Wars. I had a toy phaser that made this awesome really loud phaser sound, and I played with it non-stop until it disappeared one day. And I was sure I’d left it in the middle of my floor, like I did with all my toys, but I found it a few years later, hidden up in a closet that I couldn’t reach. And I always wondered how it got there.
Anyway, back to science fiction. For all of its inspiration, science fiction has put a few ideas into our brains which aren’t entirely helpful. You know, warp drives, artificial gravity, teleportation, and rockets that take off, fly to space, visit other planets orbiting stars, land again.
The Millennium Falcon, Firefly, and Enterprise Shuttles are all examples of single stage to orbit to orbit spacecraft, or SSTOs.
Consider the rockets that exist in reality, you know, the Atlases, Falcons and Deltas. They take off from a launch pad, fly for a bit until the fuel is used up in a stage of the rocket, then they jettison that stage and thrust with the next stage. The mighty Saturn V was so powerful that it had three stages, as it made it’s way to orbit.
Diagram of Saturn V Launch Vehicle. Credit: NASA/MSFC
As we discussed in a previous article, SpaceX is working to make the first stage, and maybe even the second stage reusable, which is a vast improvement over just letting everything burn up, but there are no rockets that actually fly to orbit and back in a single stage. In fact, using the technology we have today, it’s probably not a good idea.
Has anyone ever worked on a single stage to orbit? What technological advances will need to happen to make this work?
As I said earlier, a single stage to orbit rocket would be something like the Millennium Falcon. It carries fuel, and then uses that fuel to fly into orbit, and from world to world. Once it runs out of fuel, it gets filled up again, and then it’s off again, making the Kessel Run and avoiding Imperial Blockades.
This concept of a rocket matches our personal experience with every other vehicle we’ve ever been in. You drive your car around and refuel it, same with boats, airplanes and every other form of Earth-based transportation.
But flying into space requires the expenditure of energy that defies comprehension. Let me give you an example. A Falcon 9 rocket can lift about 22,800 kilograms into low-Earth orbit. That’s about the same as a fully loaded cement truck – which is a lot.
SpaceX Falcon 9 poised for Jan. 14, 2017, Return to Flight launch from Vandenberg Air Force Base in California carrying ten Iridium NEXT comsats to orbit. Credit: SpaceX
The entire fueled Falcon 9 weighs just over 540,000 kg, of which more than 510,000 kgs of it are fuel, with a little extra mass for the engines, fuel tanks, etc. Imagine if you drove a car that was essentially 95% fuel.
The problem is specific impulse; the maximum amount of thrust that a specific kind of engine and fuel type can achieve. I’m not going to go into all the details, but the most efficient chemical rockets we have, fueled by liquid hydrogen and oxygen, can just barely deliver enough thrust to get you to orbit. They have a maximum specific impulse of about 450 seconds.
Because the amount of fuel it takes to launch a rocket is so high, modern rockets use a staging system. Once a stage has emptied out all its fuel, it detaches and returns to Earth so that the second stage can keep going without having to drag along the extra weight of the empty fuel tanks.
After stage separation of the Falcon 9 rocket, flames are barely visible around nozzle as the second stage engine ignites and the first stage falls back to the Earth below. Credit: SpaceX
You might be surprised to know that many modern rockets are actually capable of reaching orbit with a single stage. The problem is that they wouldn’t be able to carry any significant payload.
At the end of the day, considering the chemical rockets we have today, the multi-staged profile is the most efficient and cost-effective strategy for carrying the most payload to space for the lowest cost possible.
Has anyone tried developing SSTOs in the past? Definitely. Probably the most widely publicized was NASA’s X-33/VentureStar program, developed by Lockheed Martin in the 1990s.
The proposed X-33 spacecraft. Credit: NASA
The purpose of the X-33 was to test out a range of new technologies for NASA, including composite fuel tanks, autonomous flight, and a new lifting body design.
In order to make this work, they developed a new kind of rocket engine called the “aerospike”. Unlike a regular rocket engine which provide a fixed amount of thrust, an aerospike could be throttled back like a jet engine, using less fuel at lower altitudes, where the atmosphere is thickest.
The test of twin Linear Aerospike XRS-2200 engines, originally built for the X-33 program, was performed on August 6, 2001 at NASA’s Sternis Space Center, Mississippi. The engines were fired for the planned 90 seconds and reached a planned maximum power of 85 percent. Credit: NASA’s Marshall Space Flight Center
Lockheed Martin was working on a 1/3rd scale prototype, but they struggled with many of the new technologies. In the end, their failure to be able to build a composite fuel tank that could contain the liquid oxygen and hydrogen forced them to abandon the project.
Even if they could get the technology working, so the X-33 was fully reusable, its ability to carry a payload would have been dramatically lower than a traditional multi-staged rocket.
In order to really achieve the dream of single stage to orbit, we need to step away from chemical rockets and move to a type of engine that can deliver thrust more efficiently.
We know that jets work more efficiently than rockets, because they only need to carry fuel. They pull oxygen in from the atmosphere, to burn the fuel. So one intriguing idea is to make a rocket that acts like a jet engine while in the atmosphere, and then acts like a rocket once it’s out in space.
And that’s the plan with the British Skylon rocket. It would take off from a regular runway, accelerate to about 6,600 km/h reaching an altitude of 26 kilometers. All this time, its SABRE engine would be pulling in oxygen from the atmosphere, combining it with hydrogen fuel.
An artist’s conception of Reaction Engines’ Skylon spacecraft. Credit: Reaction Engines
From this point, it would switch over to an internal liquid oxygen tank to provide oxidizer, and complete the flight to orbit. All the while using the same flexible SABRE engine. Once in orbit, it would release its 15-tonne payload and then return to Earth, landing on a runway like the space shuttle orbiter did. It’s a really creative idea.
Unfortunately, the development of the Skylon has taken a long time, with shrinking budgets limiting the amount of tests they’ve been able to do. If everything goes well, the first prototype might fly within a few years, so stay tuned to this story.
Another idea which has had some testing is the idea of a nuclear rocket. Unlike a chemical rocket, which burns fuel, and blasts it out the back for thrust, a nuclear rocket would carry a reactor on board. It would heat up some kind of working fuel, like liquid hydrogen, and then blast it out the back for propulsion.
The key elements of a NERVA solid-core nuclear-thermal engine. Credit: NASA
NASA did some tests a few decades ago with a nuclear thermal rocket called NERVA, and found that they could sustain high levels of thrust for very long periods of time. Their final prototype, provided continuous thrust for over 2 hours, including 28 minutes at full power.
NASA calculated that a nuclear-powered rocket would be roughly twice as efficient as a traditional chemical rocket. It would have a specific impulse of more than 950 seconds. But flying a nuclear rocket into space comes with a significant downside. Rockets explode. It’s bad when a chemical rocket explodes, but if a nuclear reactor detonated while making its way up through the atmosphere, it would rain down radioactive debris. For now, that’s considered too much of a risk; however, future interplanetary missions may very well use nuclear rockets.
There’s one more exotic fuel system that’s really exciting – metallic hydrogen. This solid form appears naturally at the heart of Jupiter, under the incredible pressure of the planet’s gravity. But earlier this year, researchers at Harvard finally created some in the lab. They used a tiny vice to squeeze hydrogen atoms with more force than the pressures at the center of the Earth.
Microscopic images of the stages in the creation of atomic molecular hydrogen: Transparent molecular hydrogen (left) at about 200 GPa, which is converted into black molecular hydrogen, and finally reflective atomic metallic hydrogen at 495 GPa. Credit: Isaac Silvera
It took an enormous amount of energy to squeeze hydrogen together that tightly, but in theory, once crafted, it should be relatively stable. And here’s the best part. When you ignite it, you get that energy back.
If used as a rocket fuel, it would provide a specific impulse of 1700 seconds. Compare that to the mere 450 from chemical rockets. A rocket powered by metallic hydrogen would easily get to orbit with a single stage, and travel efficiently to other planets.
Single Stage to Orbit rockets would be awesome. Science fiction has foretold it. That said, at the end of the day, whatever gets the most amount of payload into orbit for the lowest price is the most interesting rocket system. And right now, that’s staged rockets.
However, a bigger issue might be reliability and reusability. If you can get a single vehicle that takes off, travels to orbit and then returns to its launch pad, you can’t get anything simpler than that. No rockets to restack, no barges to navigate. You just use and reuse the same system again and again, and that’s a really exciting idea.
Right this moment, reusable staged rockets like SpaceX has the edge, but if and when the Skylon gets flying, I think we’ll have some serious competition.
Once we master metallic hydrogen, spaceflight will look very very different. Science reality will nearly match science fiction, and I’ll finally be able to fly my own personal Millennium Falcon.
Using two diamonds, scientists squeezed hydrogen to pressures above those in Earth's core. Credit: Sang-Heon Shim, Arizona State University
For some time, scientists have been fascinated by the concept of metallic hydrogen. Such an element is believed to exist naturally when hydrogen is placed under extreme pressures (like in the interior of gas giants like Jupiter). But as a synthetic material, it would have endless applications, since it is believed to have superconducting properties at room temperature and the ability to retain its solidity once it has been brought back to normal pressure.
For this reason, condensed matter physicists have been attempting to create metallic hydrogen for decades. And according to a recent study published in Science Magazine, a pair of physicists from the Lyman Laboratory of Physics at Harvard University claim to have done this very thing. If true, this accomplishment could usher in a new age of super materials and high-pressure physics.
The existence of metallic hydrogen was first predicted in 1935 Princeton physicists Eugene Wigner and Hillard Bell Huntington. For years, Isaac Silvera (the Thomas D. Cabot Professor at Harvard University) and Ranga Dias, a postdoctorate fellow, have sought to create it. They claim to have succeeded, using a process which they described in their recently-published study, “Observation of the Wigner-Huntington transition to metallic hydrogen“.
This cut-away illustrates a model of the interior of Jupiter, with a rocky core overlaid by a deep layer of liquid metallic hydrogen. Credit: Kelvinsong/Wikimedia Commons
Such a feat, which is tantamount to creating the heart of Jupiter between two diamonds, is unparalleled in the history of science. As Silvera described the accomplishment in a recent Harvard press release:
“This is the Holy Grail of high-pressure physics. It’s the first-ever sample of metallic hydrogen on Earth, so when you’re looking at it, you’re looking at something that’s never existed before.”
In the past, scientists have succeeded in creating liquid hydrogen at high temperature conditions by ramping up the pressures it was exposed to (as opposed to cryogenically cooling it). But metallic hydrogen has continued to elude experimental scientists, despite repeated (and unproven) claims in the past to have achieved synthesis. The reason for this is because such experiments are extremely temperamental.
For instance, the diamond anvil method (which Silvera and Dias used a variation of) consists of holding a sample of hydrogen in place with a thin metal gasket, then compressing it between two diamond-tipped vices. This puts the sample under extreme pressure, and a laser sensor is used to monitor for any changes. In the past, this has proved problematic since the pressure can cause the hydrogen to fill imperfections in the diamonds and crack them.
While protective coatings can ensure the diamonds don’t crack, the additional materials makes it harder to get accurate readings from laser measurements. What’s more, scientists attempting to experiment with hydrogen have found that pressures of ~400 gigapascals (GPa) or more need to be involved – which turns the hydrogen samples black, thus preventing the laser light from being able to penetrate it.
Microscopic images of the stages in the creation of metallic hydrogen: Transparent molecular hydrogen (left) at about 200 GPa, which is converted into black molecular hydrogen, and finally reflective atomic metallic hydrogen at 495 GPa. Credit: Isaac Silvera
For the sake of their experiment, Professors Ranga Dias and Isaac Silvera took a different approach. For starters, they used two small pieces of polished synthetic diamond rather than natural ones. They then used a reactive ion etching process to shave their surfaces, then coated them with a thin layer of alumina to prevent hydrogen from diffusing into the crystal structure.
They also simplified the experiment by removing the need for high-intensity laser monitoring, relying on Raman spectroscopy instead. When they reached a pressure of 495 GPa (greater than that at the center of the Earth), their sample reportedly became metallic and changed from black to shiny red. This was revealed by measuring the spectrum of the sample, which showed that it had become highly reflective (which is expected for a sample of metal).
As Silvera explained, these experimental results (if verified) could lead to all kinds of possibilities:
“One prediction that’s very important is metallic hydrogen is predicted to be meta-stable. That means if you take the pressure off, it will stay metallic, similar to the way diamonds form from graphite under intense heat and pressure, but remain diamonds when that pressure and heat are removed. As much as 15 percent of energy is lost to dissipation during transmission, so if you could make wires from this material and use them in the electrical grid, it could change that story.”
Superconducting links developed to carry currents of up to 20,000 amperes are being tested at CERN. Credit: CERN
In short, metallic hydrogen could speed the revolution in electronics already underway, thanks to the discovery of materials like graphene. Since metallic hydrogen is also believed to be a superconductor at room temperature, its synthetic production would have immense implications for high-energy research and physics – such as that being conducted by CERN.
Beyond that, it would also enable research into the interior’s of gas giants. For some time, scientists have suspected that a layer of metallic hydrogen may surround the cores of gas giants like Jupiter and Saturn. Naturally, the temperature and pressure conditions in the interiors of these planets make direct study impossible. But by being able to produce metallic hydrogen synthetically, scientists could conduct experiment to see how it behaves.
Naturally, the news of this experiment and its results is being met with skepticism. For instance, critics wonder if the pressure reading of 495 GPa was in fact accurate, since Silvera and Dias only obtained that as a final measurement and were forced to rely on estimates prior to that. Second, there are those who question if the reddish speck that resulted is in fact hydrogen, and some material that came from the gasket or diamond coating during the process.
However, Silvera and Dias are confident in their results and believe they can be replicated (which would go far to silence doubts about their results). For one, they emphasize that a comparative measurement of the reflective properties of the hydrogen dot and the surrounding gasket suggest that the hydrogen is pure. They also claim their pressure measurements were properly calibrated and verified.
In the future, they intend to obtain additional spectrographic readings from the sample to confirm that it is in fact metallic. Once that is done, they plan to test the sample to see if it is truly metastable, which will consist of them opening the vise and seeing if it remains in a solid state. Given the implications of success, there are many who would like to see their experiment borne out!
Be sure to check out this video produced by Harvard University that talks about the experiment:
