The Raw Materials for Life Form Early on in Stellar Nurseries

This is a two-panel mosaic of part of the Taurus Giant Molecular Cloud, the nearest active star-forming region to Earth. The darkest regions are where stars are being born. Inside these vast clouds, complex chemicals are also forming. Image Credit: Adam Block /Steward Observatory/University of Arizona

Life doesn’t appear from nothing. Its origins are wrapped up in the same long, arduous process that creates the elements, then stars, then planets. Then, if everything lines up just right, after billions of years, a simple, single-celled organism can appear, maybe in a puddle of water on a hospitable planet somewhere.

It takes time for the building blocks of stars and planets to assemble in space, and the building blocks of life are along for the ride. But there are significant gaps in our understanding of how all that works. A new study is filling in one of those gaps.

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A Martian Meteorite Contains Organic Compounds. The Raw Ingredients for Life?

Martian meteorite Tissint. (Image Credit: Dr. Ludovic Ferriere (study co-author); Natural History Museum Vienna)

In a recent study published in Sciences Advances, an international team of scientists led by the Technical University of Munich examined the Martian meteorite Tissint, which fell near the village of Tissint, Morocco, on July 18, 2011, with pieces of the meteorite found as far as approximately 50 kilometers (30 miles) from the village. What makes Tissint intriguing is the presence of a “huge organic diversity”, as noted in the study, which could help scientists better understand if life ever existed on Mars, and even the geologic history of Earth, as well.

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Comet Impacts Could Have Brought the Raw Ingredients for Life to Europa’s Ocean

An artist's concept of a comet or asteroid impact on Jupiter's moon Europa. Credit: NASA/JPL-Caltech

Jupiter is the most-visited planet in the Solar System, thanks largely to NASA. It all started with Pioneer 10 and 11, followed by Voyager 1 and 2. Those were all flyby missions, and it wasn’t until 1996 that the Galileo spacecraft became the first to orbit the gas giant and even send a probe into its atmosphere. Then in 2016, the Juno spacecraft entered orbit around Jupiter and is still there today.

All of these missions were focused on Jupiter, but along the way, they gave us tantalizing hints of the icy moon Europa. The most impactful thing we’ve learned is that Europa, though frozen on the surface, holds an ocean under all that ice. And that warm, salty ocean might contain more water than all of Earth’s oceans combined.

Might it hold life?

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NASA and HeroX are Crowdsourcing the Search for Life on Mars

This low-angle self-portrait of NASA's Curiosity Mars rover shows the vehicle at the site from which it reached down to drill into a rock target called "Buckskin." The MAHLI camera on Curiosity's robotic arm took multiple images on Aug. 5, 2015, that were stitched together into this selfie. Credits: NASA/JPL-Caltech/MSSS

For almost sixty years, robotic missions have been exploring the surface of Mars in search of potential evidence of life. More robotic missions will join in this search in the next fifteen years, the first sample return from Mars (courtesy of the Perseverance rover) will arrive here at Earth, and crewed missions will be sent there. Like their predecessors, these missions will rely on mass spectrometry to analyze samples of the Martian sands to look for potential signs of past life.

Given how much data we can expect from these missions, NASA is looking for new methods to analyze geological samples. To this end, NASA has partnered with the global crowdsourcing platform HeroX and the data-science company DrivenData to launch the Mars Spectrometry: Detect Evidence for Past Life challenge. With a prize purse of $30,000, this Challenge seeks innovative methods that rely on machine learning to automatically analyze Martian geological samples for potential signs of past life.

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ExoMars Will be Drilling 1.7 Meters to Pull its Samples From Below the Surface of Mars

In about a year (Sept. 20th, 2022), the Rosalind Franklin rover will depart for Mars. As the latest mission in the ESA’s and Roscosmos’ ExoMars program, Rosalind Franklin will join the small army of orbiters, landers, and rovers that are working to characterize the Martian atmosphere and environment. A key aspect of the rover’s mission will involve drilling into the Martian soil and rock and obtaining samples from deep beneath the surface.

To prepare for drilling operations on Mars, the ESA, Italian space agency (ASI), and their commercial partners have been conducting tests with a replica – aka. the Ground Test Model (GTM). Recently, the test model completed its first round of sample collection, known as the Mars Terrain Simulation (MTS). The rover drilled into hard stone and extracted samples from 1.7 meters (5.5 feet) beneath the surface in a record-breaking feat.

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Organic Material Found on an Asteroid Sample Returned by Hayabusa 1

Panspermia is an idea that has been around for a long time.  It was first mentioned in the 5th century BC by Anaxagoras, one of the most prominent pre-Socratic philosophers.  The problem with the theory is that there’s never really been any evidence to back it up.  That lack of evidence has changed dramatically in the last 20 or so years, and recently more data has been added to that dataset.  A team from Royal Holloway, part of the University of London, found organic material and water in a sample of Itokawa, the asteroid the first Hayabusa mission visited over 10 years ago.

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Curiosity Sniffs a Spike in Methane. Could it be a Sign of Life?

This low-angle self-portrait of NASA's Curiosity Mars rover shows the vehicle at the site from which it reached down to drill into a rock target called "Buckskin" on lower Mount Sharp. Credits: NASA/JPL-Caltech/MSSS

Since it landed on Mars in 2012, one of the main scientific objectives of the Curiosity rover has been finding evidence of past (or even present) life on the Red Planet. In 2014, the rover may have accomplished this very thing when it detected a tenfold increase in atmospheric methane in its vicinity and found traces of complex organic molecules in drill samples while poking around in the Gale Crater.

About a year ago, Curiosity struck pay dirt again when it found organic molecules in three-billion-year-old sedimentary rocks located near the surface of lower Mount Sharp. But last week, the Curiosity rover made an even more profound discovery when it detected the largest amount of methane ever measured on the surface of Mars – about 21 parts per billion units by volume (ppbv).

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A Star’s Outburst is Releasing Organic Molecules Trapped in the ice Around it

Artist’s impression of the protoplanetary disk around a young star V883 Ori. The outer part of the disk is cold and dust particles are covered with ice. ALMA detected various complex organic molecules around the snow line of water in the disk. Credit: National Astronomical Observatory of Japan

According to widely-accepted theories, the Solar System formed roughly 4.6 billion years ago from a massive cloud of dust and gas (aka. Nebular Theory). This process began when the nebula experienced a gravitational collapse in the center that became our Sun. The remaining dust and gas formed a protoplanetary disk that (over time) accreted to form the planets.

However, scientists remain unsure about when organic molecules first appeared in our Solar System. Luckily, a new study by an international team of astronomers may be able to help answer that question. Using the Atacama Large Millimeter-submillimeter Array (ALMA), the team detected complex organic molecules around the young star V883 Ori, which could someday lead to the emergence of life in that system.

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Complex Organics Molecules are Bubbling up From Inside Enceladus

Cryvolcanism at Enceladus, a moon of Satury. This Cassini narrow-angle camera image looks across the south pole of Enceladus and its geysers of material. Credit: NASA/JPL-Caltech/Space Science Institute/. Pluto is known to have cryovolcanoes, too.
Cryvolcanism at Enceladus, a moon of Satury. This Cassini narrow-angle camera image looks across the south pole of Enceladus and its geysers of material. Credit: NASA/JPL-Caltech/Space Science Institute

The Cassini orbiter revealed many fascinating things about the Saturn system before its mission ended in September of 2017. In addition to revealing much about Saturn’s rings and the surface and atmosphere of Titan (Saturn’s largest moon), it was also responsible for the discovery of water plumes coming from Enceladus‘ southern polar region. The discovery of these plumes triggered a widespread debate about the possible existence of life in the moon’s interior.

This was based in part on evidence that the plumes extended all the way to the moon’s core/mantle boundary and contained elements essential to life. Thanks to a new study led by researchers from of the University of Heidelberg, Germany, it has now been confirmed that the plumes contain complex organic molecules. This is the first time that complex organics have been detected on a body other than Earth, and bolsters the case for the moon supporting life.

The study, titled “Macromolecular organic compounds from the depths of Enceladus“, recently appeared in the journal Nature. The study was led by Frank Postberg and Nozair Khawaja of the Institute for Earth Sciences at the University of Heidelberg, and included members from the Leibniz Institute of Surface Modification (IOM), the Southwest Research Institute (SwRI), NASA’s Jet Propulsion Laboratory, and multiple universities.

The “tiger stripes” of Enceladus, as pictured by the Cassini space probe. Credit: NASA/JPL/ESA

The existence of a liquid water ocean in Enceladus’ interior has been the subject of scientific debate since 2005, when Cassini first observed plumes containing water vapor spewing from the moon’s south polar surface through cracks in the surface (nicknamed “Tiger Stripes”). According to measurements made by the Cassini-Huygens probe, these emissions are composed mostly of water vapor and contain molecular nitrogen, carbon dioxide, methane and other hydrocarbons.

The combined analysis of imaging, mass spectrometry, and magnetospheric data also indicated that the observed southern polar plumes emanate from pressurized subsurface chambers. This was confirmed by the Cassini mission in 2014 when the probe conducted gravity measurements that indicated the existence of a south polar subsurface ocean of liquid water with a thickness of around 10 km.

Shortly before the probe plunged into Saturn’s atmosphere, the probe also obtained data that indicated that the interior ocean has existed for some time. Thanks to previous readings that indicated the presence of hydrothermal activity in the interior and simulations that modeled the interior, scientists concluded that if the core were porous enough, this activity could have provided enough heat to maintain an interior ocean for billions of years.

However, all the previous studies of Cassini data were only able to identify simple organic compounds in the plume material, with molecular masses mostly below 50 atomic mass units. For the sake of their study, the team observed evidence of complex macromolecular organic material in the plumes’ icy grains that had masses above 200 atomic mass units.

Hydrothermal activity in Enceladus’ core and the rise of organic-rich bubbles. Credit and Copyright: ESA; F. Postberg et al (2018)

This constitutes the first-ever detection of complex organics on an extraterrestrial body. As Dr. Khawaja explained in a recent ESA press release:

“We found large molecular fragments that show structures typical for very complex organic molecules. These huge molecules contain a complex network often built from hundreds of atoms of carbon, hydrogen, oxygen and likely nitrogen that form ring-shaped and chain-like substructures.”

The molecules that were detected were the result of the ejected ice grains hitting the dust-analyzing instrument aboard Cassini at speeds of about 30,000 km/hour. However, the team believes that these were mere fragments of larger molecules contained beneath Enceladus’ icy surface. As they state in their study, the data suggests that there is a thin organic-rich film on top of the ocean.

These large molecules would be the result of by complex chemical processes, which could be those related to life. Alternately, they may be derived from primordial material similar to what has been found in some meteorites or (as the team suspects) that is generated by hydrothermal activity. As Dr. Postberg explained:

“In my opinion the fragments we found are of hydrothermal origin, having been processed inside the hydrothermally active core of Enceladus: in the high pressures and warm temperatures we expect there, it is possible that complex organic molecules can arise.”

Artist rendering showing an interior cross-section of the crust of Enceladus, which shows how hydrothermal activity may be causing the plumes of water at the moon’s surface. Credits: NASA-GSFC/SVS, NASA/JPL-Caltech/Southwest Research Institute

As noted, recent simulations have shown the moon could be generating enough heat through hydrothermal activity for its interior ocean to have existed for billions of years. This study follows up on that scenario by showing how organic material could be injected into the ocean by hydrothermal vents. This is similar to what happens on Earth, a process that scientists believe may have played a vital role in the origins of life on our planet.

On Earth, organic substances are able to accumulate on the walls of rising air bubbles created by hydrothermal vents, which then rise to the surface and are dispersed by sea spray and the bubbles bursting. Scientists believe a similar process is happening on Enceladus, where bubbles of gas rising through the ocean could be bringing organic materiel up from the core-mantle boundary to the icy surface.

When these bubbles burst at the surface, it helps disperse some of the organics which then become part of the salty spray coming through the tiger cracks. This spray then freezes into icy particles as it reaches space, sending organic material and ice throughout the Saturn System, where it has now been detected. If this study is correct, then another fundamental ingredient for life is present in Enceladus’ interior, making the case for life there that much stronger.

This is just the latest in a long-line of discoveries made by Cassini, many of which point to the potential existence of life on or in some of Saturn’s moons. In addition to confirming the first organic molecules in an “ocean world” of our Solar System, Cassini also found compelling evidence of a rich probiotic environment and organic chemistry on Titan.

In the future, multiple missions are expected to return to these moons to gather more evidence of potential life, picking up where the venerable Cassini left off. So long Cassini, and thanks for blazing a trail!

Further Reading: ESA, Nature

There’s Sand on Titan, Where Does it Come From?

This true-color image of Titan, taken by the Cassini spacecraft, shows the moon's thick, hazy atmosphere. Image: By NASA - http://photojournal.jpl.nasa.gov/catalog/PIA14602, Public Domain, https://commons.wikimedia.org/w/index.php?curid=44822294
This true-color image of Titan, taken by the Cassini spacecraft, shows the moon's thick, hazy atmosphere. Credit: NASA

Even though the Cassini orbiter ended its mission on of September 15th, 2017, the data it gathered on Saturn and its largest moon, Titan, continues to astound and amaze. During the thirteen years that it spent orbiting Saturn and conducting flybys of its moons, the probe gathered a wealth of data on Titan’s atmosphere, surface, methane lakes, and rich organic environment that scientists continue to pore over.

For instance, there is the matter of the mysterious “sand dunes” on Titan, which appear to be organic in nature and whose structure and origins remain have remained a mystery. To address these mysteries, a team of scientists from John Hopkins University (JHU) and the research company Nanomechanics recently conducted a study of Titan’s dunes and concluded that they likely formed in Titan’s equatorial regions.

Their study, “Where does Titan Sand Come From: Insight from Mechanical Properties of Titan Sand Candidates“, recently appeared online and has been submitted to the Journal of Geophysical Research: Planets. The study was led by Xinting Yu, a graduate student with the Department of Earth and Planetary Sciences (EPS) at JHU, and included EPS Assistant Professors Sarah Horst (Yu’s advisor) Chao He, and Patricia McGuiggan, with support provided by Bryan Crawford of Nanomechanics Inc.

To break it down, Titan’s sand dunes were originally spotted by Cassini’s radar instruments in the Shangri-La region near the equator. The images the probe obtained showed long, linear dark streaks that looked like wind-swept dunes similar to those found on Earth. Since their discovery, scientists have theorized that they are comprised of grains of hydrocarbons that have settled on the surface from Titan’s atmosphere.

In the past, scientists have conjectured that they form in the northern regions around Titan’s methane lakes and are distributed to the equatorial region by the moon’s winds. But where these grains actually came from, and how they came to be distributed in these dune-like formations, has remained a mystery. However, as Yu explained to Universe Today via email, that is only part of what makes these dunes mysterious:

“First, nobody expected to see any sand dunes on Titan before the Cassini-Huygens mission, because global circulation models predicted the wind speeds on Titan are too weak to blow the materials to form dunes. However, through Cassini we saw vast linear dune fields that covers almost 30% of the equatorial regions of Titan!

“Second, we are not sure how Titan sands are formed.Dune materials on Titan are completely different from those on Earth. On Earth, dune materials are mainly silicate sand fragments weathered from silicate rocks. While on Titan, dune materials are complex organics formed by photochemistry in the atmosphere, falling to the ground. Studies show that the dune particles are pretty big (at least 100 microns), while the photochemistry formed organic particles are still pretty small near the surface (only around 1 micron). So we are not sure how the small organic particles are transformed into the big sand dune particles (you need a million small organic particles to form one single sand particle!)

“Third, we also don’t know where the organic particles in the atmosphere are processed to become bigger to form the dune particles. Some scientists think these particles can be processed everywhere to form the dune particles, while some other researchers believe their formation need to be involved with Titan’s liquids (methane and ethane), which are currently located only in the polar regions.”

Dunes on Titan seen in Cassini’s radar (top) that are similar to Namibian sand dunes on Earth. The features that appear to be clouds in the top picture are actually topographic features. Credit: NASA

To shed light on this, Yu and her colleagues conducted a series of experiments to simulate materials being transported on both terrestrial and icy bodies. This consisted of using several natural Earth sands, such as silicate beach sand, carbonate sand and white gyspum sand. To simulate the kinds materials found on Titan, they used laboratory-produced tholins, which are molecules of methane that have been subjected to UV radiation.

The production of tholins was specifically conducted to recreate the kinds of organic aerosols and photochemistry conditions that are common on Titan. This was done using the Planetary HAZE Research (PHAZER) experimental system at Johns Hopkins University – for which the Principal Investigator is Sarah Horst. The last step consisted of using a nanoidentification technique (overseen by Bryan Crawford of Nanometrics Inc.) to study the mechanical properties of the simulated sands and tholins.

This consisted of placing the sand simulants and tholins into a wind tunnel to determine their mobility and see if they could be distributed in the same patterns. As Yu explained:

“The motivation behind the study is to try to answer the third mystery. If the dune materials are processed through liquids, which are located in the polar regions of Titan, they need to be strong enough to be transported from the poles to the equatorial regions of Titan, where most of the dunes are located. However, the tholins we produced in the lab are in extremely low amounts: the thickness of the tholin film we produced is only around 1 micron, about 1/10-1/100 of the thickness of human hair. To deal with this, we used a very intriguing and precise nanoscale technique called nanoindentation to perform the measurements. Even though the produced indents and cracks are all in nanometer scales, we can still precisely determine mechanical properties like Young’s modulus (indicator of stiffness), nanoindentation hardness (hardness), and fracture toughness (indicator of brittleness) of the thin film.”

Radar image of sand dunes on Titan. Credit: NASA/JPL–Caltech/ASI/ESA and USGS/ESA

In the end, the team determined that the organic molecules found on Titan are much softer and more brittle when compared to even the softest sands on Earth. Simply put, the tholins they produced did not appear to have the strength to travel the immense distance that lies between Titan’s northern methane lakes and the equatorial region. From this, they concluded that the organic sands on Titan are likely formed near where they are located.

“And their formation may not involve liquids on Titan, since that would require a huge transportation distance of over 2000 kilometers from the Titan’s poles to the equator,” Yu added. “The soft and brittle organic particles would be grinded to dust before they reach the equator. Our study used a completely different method and reinforced some of results inferred from Cassini observations.”

In the end, this study represents a new direction for researchers when it comes to the study of Titan and other bodies in the Solar System. As Yu explained, in the past, researchers were mostly constrained with Cassini data and modelling to answer questions about Titan’s sand dunes. However, Yu and her colleagues were able to use laboratory-produced analogs to address these questions, despite the fact that the Cassini mission is now at an end.

What’s more, this most recent study is sure to be of immense value as scientists continue to pore over Cassini’s data in anticipation of future missions to Titan. These missions aim to study Titan’s sand dunes, methane lakes and rich organic chemistry in more detail. As Yu explained:

“[O]ur results can not only help understand the origin of Titan’s dunes and sands, but also it will provide crucial information for potential future landing missions on Titan, such as Dragonfly (one of two finalists (out of twelve proposals) selected for further concept development by NASA’s New Frontiers program). The material properties of the organics on Titan can actually provide amazing clues to solve some of the mysteries on Titan.

“In a study we published last year in JGR-planets (2017, 122, 2610–2622), we found out that the interparticle forces between tholin particles are much larger than common sand on Earth, which means the organics on Titan are much more cohesive (or stickier) than silicate sands on Earth. This implies that we need a larger wind speed to blow the sand particles on Titan, which could help the modeling researchers to answer the first mystery. It also suggests that Titan sands could be formed by simple coagulation of organic particles in the atmosphere, since they are much easier to stick together. This could help understand the second mystery of Titan’s sand dunes.”

Artist’s concept of the dragonfly being deployed to Titan and commencing its exploration mission. Credit: APL/Michael Carroll

In addition, this study has implications for the study of bodies other than Titan. “We have found organics on many other solar system bodies, especially icy bodies in the outer solar system, such as Pluto, Neptune’s moon Triton, and comet 67P,” said Yu. “And some of the organics are photochemically produced similarly to Titan. And we do found wind blown features (called aeolian features) on those bodies as well, so our results could be applied to these planetary bodies as well.”

In the coming decade, multiple missions are expected to explore the moons of the outer Solar System and reveal things about their rich environments that could help shed light on the origins of life here on Earth. In addition, the James Webb Space Telescope (now expected to be deployed in 2021) will also use its advanced suit of instruments to study the planets of the Solar System in the hopes of address these burning questions.

Further Reading: arXiv